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They would have the most intense and wholesome hugs nobody convinces me otherwise >:0
And I am sure that law would hide all his love for tender moments but cmon bro we saw those corazon flashbacks deep inside he is craving unconditional puppy love and a lot of smoochies
And luffy being himself would just be happily obsessed a couple weeks after finding that out , like he would bombard law with muah just for the sake of law trying to hide his reactions